Metal-Oxo Cluster Catalysts for Photocatalytic Water Splitting and Carbon Dioxide Reduction
نویسندگان
چکیده
Abstract Photocatalytic water splitting and carbon dioxide photoreduction are considered effective strategies for alleviating the energy crisis environmental pollution. Polynuclear metal-oxo clusters possess excellent electron storage/release ability unique catalytic properties via intermetallic synergy, which enables them with great potential in environmentally friendly photosynthesis. Importantly, precise structure can not only act as high-efficiency catalysts but also provide well-defined structural models exploring structure–activity relationships. In this review, we systematically summarize recent progress application of polynuclear clusters, including polyoxometalate low-cost transition metal metal-oxo-cluster-based metal–organic frameworks CO 2 reduction. Furthermore, discuss challenges solutions to problems - oxo photocatalysis.
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ژورنال
عنوان ژورنال: Transactions of Tianjin University
سال: 2022
ISSN: ['1006-4982', '1995-8196']
DOI: https://doi.org/10.1007/s12209-022-00324-z